The title compound, C(22)H(24)OSi or Ph(3)SiO(t)Bu, shows a distorted tetra-hedral coordination sphere around the Si atom. The C-O-Si angle is 135.97â (12)° and the O-Si distance is 1.6244â (13)â à . The mol-ecules are held together by weak inter-actions only. An Hâ¯H distance of 2.2924â (7)â à is found between aryl H atoms and is the shortest inter-molecular distance in the structure. With regard to the broad applicability of R(3)SiO structural motifs in all fields of chemistry, the mol-ecule demonstrates a common model system for silicon centers surrounded by sterically demanding substituents.
tert-Butoxy-triphenyl-silane.
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作者:Bauer Jonathan O, Strohmann Carsten
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Jan 27; 66(Pt 2):o461-2 |
| doi: | 10.1107/S1600536810002722 | ||
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