In the title compound, C13H14O5, the furan ring is essentially planar [maximum deviation = 0.031â (3)â à ] with a stereogenic center (R) at the sp (3) hybridized C atom. The C atom bearing the dihy-droxy ethyl group is S. The absolute configuration is based on the precursor in the synthesis. The two O-H groups are in an anti conformation with respect to each other. The mean plane of the furan-one group is twisted by 8.2â (4)° from that of the phenyl ring. In the crystal, mol-ecules are linked by O-Hâ¯O hydrogen bonds involving furan-one C=O groups and symmetry-related hy-droxy groups, forming a two-dimensional network parallel to (001). Weak C-Hâ¯O hydrogen bonds are observed within the two-dimensional network.
Crystal structure of (5R)-5-[(1S)-1,2-di-hydroxy-eth-yl]-4-meth-oxy-3-phenyl-2,5-di-hydro-furan-2-one.
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作者:Kote Santosh R, Thopate Shankar R, Gupta Sushil K, Butcher Ray J
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2014 | 起止号: | 2014 Sep 30; 70(Pt 10):o1141-2 |
| doi: | 10.1107/S1600536814021370 | ||
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