In the title compound, C22H19NOS, the cyclo-hexene ring of the tetra-hydro-benzo-thio-phenyl ring system adopts a slightly distorted half-chair conformation and is twisted slightly [7.5â (8)° for the major disorder component] from the mean plane of the thio-phene ring. The dihedral angles between the mean planes of the thio-phene ring and the phenyl rings are 65.7â (3) and 8.3â (4)°. The phenyl rings are twisted with respect to each other by 73.8â (7)°. Disorder was modeled for four C atoms of the cyclo-hexene ring over two sets of sites with an occupancy ratio of 0.659â (2):0.341â (2). In the crystal, a single weak C-Hâ¯O inter-action links the mol-ecules into [001] chains.
[2-(Benzyl-idene-amino)-4,5,6,7-tetra-hydro-benzo[b]thio-phen-3-yl](phen-yl)methanone.
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作者:Kaur Manpreet, Jasinski Jerry P, Kavitha Channappa N, Yathirajan Hemmige S, Byrappa K
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2014 | 起止号: | 2014 Apr 2; 70(Pt 5):o507-8 |
| doi: | 10.1107/S1600536814006679 | ||
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