In the binuclear title compound, [Mo(2)(C(12)H(15)N(4)O(2))(2)Cl(2)O(3)]·H(2)O, the complex mol-ecules have approximate C(2) symmetry. Both Mo(V) atoms have a distorted octa-hedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand binds to the Mo(V) atom via an N(2)O donor set. The water mol-ecule bridges two complex mol-ecules, forming O-Hâ¯O and O-Hâ¯Cl hydrogen bonds to the acetate group and to the chloride ligands.
μ-Oxido-bis{[2,2-bis-(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κN,O,N]chloridooxidomolybdenum(V)} mono-hydrate.
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作者:GolobiÄ Amalija, Ceh Boris
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Nov 24; 66(Pt 12):m1648-9 |
| doi: | 10.1107/S1600536810045393 | ||
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