The asymmetric unit of the title complex, [Ni(C(31)H(28)N(2)O(2))], comprises two crystallographically independent mol-ecules. The geometry around the Ni(II) atom in each mol-ecule is distorted square planar. The dihedral angles between the two phen-oxy rings in each mol-ecule are 17.8â (4) and 36.5â (4)°. The crystal packing is stabilized by weak Ï-Ï inter-actions [centroid-centroid distance = 3.758â (5)â à ] and C-Hâ¯Ï inter-actions.
{2,2'-[(2,2-Dimethyl-propane-1,3-diyl-dinitrilo)-bis-(phenyl-methyl-idyne)]-diphenolato}nickel(II).
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作者:Kargar Hadi, Kia Reza, Moghadam Majid, Froozandeh Fatemeh, Tahir Muhammad Nawaz
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Sep 1; 67(Pt 9):m1173 |
| doi: | 10.1107/S1600536811029813 | ||
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