Earth orbital rhythms links timing of Deccan trap volcanism phases and global climate change.

At the end of the Cretaceous, the massive Deccan trap (DT) volcanic eruptions are regarded as the primary driver of global climate deterioration. Accurate age models are key to unravel the sequence of events related to DT volcanism onset and effects on the global climate system. We establish a direct geochemical link between DT volcanism as recorded in marine osmium isotopic data and global climate change documented in benthic foraminifera carbon and oxygen isotope records. Based on our state-of-the-art astronomically calibrated age model, two major shifts in marine (187)Os/(188)Os at 66.49 and 66.28 million years ago are contemporaneous with major eruption phases of the DT and disruptions of the global carbon cycle. Geochemical records and modeling suggest larger erupted volumes with high volatile emissions for the early phase of DT volcanism and point to differing emissions of SO(2) and CO(2) during the observed marine osmium shifts with diverse effects on the global climate system.