The title compound, C(26)H(21)Cl(2)NO, crystallizes with two symmetry-independent mol-ecules (A and B) in the asymmetric unit. In both mol-ecules, the central heterocyclic ring adopts a sofa conformation. The dihedral angles between the planar part of this central heterocyclic ring [maximum deviations of 0.011â (1) and 0.036â (1)â à in mol-ecules A and B, respectively] and the two almost planar [maximum deviations of 0.020â (1) and 0.008â (1)â à in A and 0.007â (1) and 0.011â (1) in B] side-chain fragments that include the aromatic ring and bridging atoms are 20.1â (1) and 31.2â (1)° in mol-ecule A, and 26.4â (1) and 19.6â (1)° in mol-ecule B. The dihedral angles between the planar part of the heterocyclic ring and the benzyl substituent are 79.7â (1) and 53.2â (1)° in mol-ecules A and B, respectively. In the crystal, weak inter-molecular C-Hâ¯O hydrogen bonds link the two independent mol-ecules into dimers.
1-Benzyl-3,5-bis-(4-chloro-benzyl-idene)piperidin-4-one.
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作者:Nesterov Volodymyr V, Sarkisov Sergey S, Shulaev Vladimir, Nesterov Vladimir N
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Jun 1; 67(Pt 6):o1505-6 |
| doi: | 10.1107/S1600536811018587 | ||
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