Stereoselective synthesis of 2,3-diazido-2,3-dideoxy-β-d-mannosides has been accomplished via Cs(2)CO(3)-mediated anomeric O-alkylation of 2,3-diazido-2,3-dideoxy-β-d-mannoses with primary electrophiles. Selective oxidation of the C6 primary alcohol of the 2,3-diazido-2,3-dideoxy-β-d-mannoside successfully produced corresponding 2,3-diazido-2,3-dideoxy-β-d-mannuronic acid.
Synthesis of 2,3-diazido-2,3-dideoxy-β-d-mannosides and 2,3-diazido-2,3-dideoxy-β-d-mannuronic acid via stereoselective anomeric O-alkylation.
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作者：Banjara Rama, Thapa Prakash, Kela Shailja Hitesh, Wu Fenglang, Zhu Jianglong
| 期刊： | Carbohydrate Research | 影响因子： | 2.500 |
| 时间： | 2024 | 起止号： | 2024 Nov;545:109279 |
| doi： | 10.1016/j.carres.2024.109279 | ||
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