The title compound, C21H23NSi, was synthesized by Sonogashira-type reaction of 1-ethyl-3-iodo-2-phenyl-1H-indole with tri-methyl-silyl-acetyl-ene. The indole ring system is nearly planar [maximum atomic deviation = 0.0244â (15)â à ] and is oriented at a dihedral angle of 51.48â (4)° with respect to the phenyl ring. The supramolecular aggregation is completed by weak C-Hâ¯Ï inter-actions of the methylene and phenyl groups with the benzene and pyrrole rings of the indole ring system. The methyl groups of the tri-methyl-silyl unit are equally disordered over two sets of sites.
1-Ethyl-2-phenyl-3-[2-(tri-methyl-sil-yl)ethyn-yl]-1H-indole.
1-乙基-2-苯基-3-[2-(三甲基硅基)乙炔基]-1H-吲哚
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作者:Baglai Iaroslav, Maraval Valérie, Duhayon Carine, Chauvin Remi
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 May 18; 69(Pt 6):o921-2 |
| doi: | 10.1107/S1600536813012671 | ||
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