In the title compound, {[Cd(C(9)H(5)BrO(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Cd(II) atom has a distorted octa-hedral coordination geometry. Two N atoms from two 4,4'-bipyridine (bipy) ligands occupy the axial positions, while the equatorial positions are furnished by three carboxyl-ate O atoms from three 3-bromo-2-(carboxyl-atometh-yl)benzoate (bcb) ligands and one O atom from a water mol-ecule. The bipy and bcb ligands link the Cd(II) atoms into a three-dimensional network. O-Hâ¯O hydrogen bonds and Ï-Ï inter-actions between the pyridine and benzene rings [centroid-centroid distance = 3.736â (4)â à ] are present in the crystal.
Poly[[aqua-(μ(2)-4,4'-bipyridine-κ(2)N:N')[μ(3)-3-bromo-2-(carboxyl-atometh-yl)-benzoato-κ(3)O(1):O(1'):O(2)]cadmium] monohydrate].
聚[[水合-(α(2)-4,4'-联吡啶-α(2)N:N')[α(3)-3-溴-2-(羧基-原子甲基)-苯甲酸根-α(3)O(1):O(1'):O(2)]镉]一水合物]
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作者:Liu Yangmei, Cao Kai, Wang Fenglin
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Aug 1; 68(Pt 8):m1071 |
| doi: | 10.1107/S1600536812031297 | ||
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