In the title compound, [Cu(ClO(4))(2)(CH(3)CN)(2)(H(2)O)(2)], the Cu(2+) ion, located on a special position (site symmetry [Formula: see text]), is coordinated by six monodentate ligands, viz. an N-coordin-ated acetonitrile, a perchlorate anion and a water mol-ecule, and their symmetry-related counterparts. The perchlorate anion is disordered over two sets of sites with occupancies of 0.53â (2) and 0.47â (2). The crystal structure is stabilized by O-Hâ¯O hydrogen bonds involving the perchlorate ion and aqua H atoms.
Bis(acetonitrile-κN)diaqua-bis-(perchlorato-κO)copper(II).
双(乙腈-γN)diaqua-双-(高氯酸-γO)铜(II)
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作者:Tafeenko Viktor A, Gurskiy Stanislav I, Aslanov Leonid A
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Aug 1; 67(Pt 8):m1125-6 |
| doi: | 10.1107/S1600536811027309 | ||
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