In the crystal structure of the title compound, [Mo(C(27)H(24)N(2)O(2))O(2)]·1.75CH(2)Cl(2), the Mo(VI) ion is coordinated by two oxide O atoms and by two O and two N atoms of the tetra-dentate 1,1'-[(2,2-dimethyl-propane-1,3-di-yl)bis-(nitrilo-methyl-idyne)]di-2-naphtholate Schiff base ligand in a distorted octa-hedral configuration. The compound crystallizes with 1.75â mol-ecules of dichloro-methane per complex mol-ecule. In the crystal, symmetry-related mol-ecules are linked by a number of C-Hâ¯O inter-actions involving both the Schiff base ligand and the partly disordered dichloro-methane solvent mol-ecules, leading to the formation of a two-dimensional network extending parallel to (101).
{1,1'-[(2,2-Dimethyl-propane-1,3-di-yl)bis-(nitrilo-methyl-idyne)]di-2-naphthol-ato}dioxidomolybdenum(VI) dichloro-methane 1.75-solvate.
{1,1'-[(2,2-二甲基丙烷-1,3-二基)双-(亚硝基甲基炔)]二-2-萘酚-ato}二氧化钼(VI)二氯甲烷1.75-溶剂化物
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作者:Monadi Niaz, Sheikhshoaie Iran, Rezaeifard Abdoreza, Stoeckli-Evans Helen
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Aug 22; 65(Pt 9):m1124-5 |
| doi: | 10.1107/S1600536809032759 | ||
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