The asymmetric unit of the title compound, [Cu(C(21)H(24)N(2)O(4))]·H(2)O, comprises half of a Schiff base complex and a water mol-ecule. The Cu(II) atom, water mol-ecule and one C atom of the central propyl-ene segment are located on a twofold rotation axis. The geometry around the Cu(II) atom is distorted square-planar, supported by the N(2)O(2) donor atoms of the coordinating ligand. The dihedral angle between the symmetry-related benzene rings is 42.56â (19)°. In the crystal, O-Hâ¯O hydrogen bonds involving the water mol-ecule make an R(2) (1)(6) ring motif. Complex mol-ecules are linked into a chain along the c axis via C-Hâ¯O inter-actions.
{4,4'-Dimeth-oxy-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato}copper(II) monohydrate.
{4,4'-二甲氧基-2,2'-[2,2-二甲基丙烷-1,3-二基双(亚硝基亚甲基)]二酚酸根}铜(II)一水合物
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作者:Ganji Fatemeh, Kargar Hadi, Kia Reza, Mirkhani Valiollah, Tahir Muhammad Nawaz
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Oct 1; 68(Pt 10):m1255 |
| doi: | 10.1107/S1600536812038135 | ||
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