{Bis[2-(dicyclo-hexyl-phosphino)phen-yl]methyl-silyl-κP,Si,P'}chloridoplatinum(II).

{双[2-(二环己基膦基)苯基]甲基硅基-κP,Si,P'}氯化铂(II)

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作者:Li Yong-Hua, Zhang Yuan, Zhao Min-Min, Li Xian
In the title compound, [Pt(C(37)H(55)P(2)Si)Cl], prepared from MeSiH[(cy)(2)PC(6)H(4)](2) and [Pt(cod)Cl(2)] (cy = cyclo-hexyl; cod = cyclo-octa-1,5-diene), the Pt(II) atom is coordinated by two P atoms, one Si atom and one Cl atom in a distorted square-planar geometry. The two P atoms are in a trans arrangement and the four cyclo-hexane rings adopt a chair conformation.

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