In the title salt, [Ni(C(7)H(6)NO(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, the Ni(II) cation is O,O'-chelated by the benzoate anion and N,N',N'',N'''-chelated by the macrocycle ligand, confering a distorted octa-hedral geometry on the metal atom. The complex cations, perchlorate anions and uncoordinated water mol-ecules are linked by N-Hâ¯O and O-Hâ¯O hydrogen bonds into a three-dimensional network. The perchlorate ion is disordered over two positions in a 0.554â (8):0.446â (8) ratio.
(2-Amino-benzoato-κO,O')(rac-5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-aza-cyclo-tetra-decane-κN,N',N'',N''')nickel(II) perchlorate monohydrate.
(2-氨基苯甲酸-γO,O')(rac-5,5,7,12,12,14-六甲基-1,4,8,11-四氮杂-环四癸烷-γN,N',N'',N''')高氯酸镍(II)一水合物
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作者:Ou Guang-Chuan, Ng Seik Weng
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Sep 25; 66(Pt 10):m1295-6 |
| doi: | 10.1107/S1600536810037116 | ||
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