In the title centrosymmetric binuclear complex, [Cd(2)(NO(2))(4)(C(11)H(9)N(5))(2)], the unique Cd(II) ion is in a distorted dodeca-hedral CdN(3)O(5) coordination environment. The two inversion-related Cd(II) ions are separated by 3.9920â (6)â Ã and are bridged by two O atoms from two nitrite ligands. There are two types of Ï-Ï stacking inter-actions involving symmetry-related pyrazole rings, with centroid-centroid distances of 3.445â (2) and 3.431â (2)â Ã .
Di-μ-nitrito-κO:O,O';κO,O':O-bis-{[2,6-bis-(pyrazol-1-yl-κN)pyridine-κN](nitrito-κO,O')cadmium(II)}.
二-μ-亚硝基-γoO:O,O';γoO,O':O-双-{[2,6-双-(吡唑-1-基-γN)吡啶-γoN](亚硝基-γoO,O')镉(II)}
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作者:Sun Ting Ting, Meng Lin, Shi Jing Min
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Oct 7; 65(Pt 11):m1318 |
| doi: | 10.1107/S1600536809039841 | ||
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