Tetra-aqua-bis-(2-methyl-1H-benzimidazolium-1,3-diacetato-κO)cobalt(II) tetra-hydrate.

四水双(2-甲基-1H-苯并咪唑鎓-1,3-二乙酸-γO)钴(II)四水合物

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作者:Feng Xiu-Ling, Zhang Yu-Ping
In the title compound, [Co(C(12)H(11)N(2)O(4))(2)(H(2)O)(4)]·4H(2)O, the Co(II) atom lies on an inversion center and is octa-hedrally coordinated by six O atoms from four water mol-ecules and two monodentate zwitterionic 2-methyl-benzimidazolium-1,3-diacetate ligands. An intra-molecular O-H⋯O hydrogen bond occurs. In the crystal, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network. π-π inter-actions between the imidazole and benzene rings [centroid-centroid distance = 3.9031†(17)†à ] consolidate the crystal packing.

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