In the title compound, [Co(C(12)H(11)N(2)O(4))(2)(H(2)O)(4)]·4H(2)O, the Co(II) atom lies on an inversion center and is octa-hedrally coordinated by six O atoms from four water mol-ecules and two monodentate zwitterionic 2-methyl-benzimidazolium-1,3-diacetate ligands. An intra-molecular O-Hâ¯O hydrogen bond occurs. In the crystal, inter-molecular O-Hâ¯O hydrogen bonds link the mol-ecules into a three-dimensional network. Ï-Ï inter-actions between the imidazole and benzene rings [centroid-centroid distance = 3.9031â (17)â à ] consolidate the crystal packing.
Tetra-aqua-bis-(2-methyl-1H-benzimidazolium-1,3-diacetato-κO)cobalt(II) tetra-hydrate.
四水双(2-甲基-1H-苯并咪唑鎓-1,3-二乙酸-γO)钴(II)四水合物
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作者:Feng Xiu-Ling, Zhang Yu-Ping
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Sep 1; 67(Pt 9):m1170 |
| doi: | 10.1107/S1600536811029059 | ||
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