In the title compound, [Pd(C(5)H(4)NS)(C(18)H(14)PS)(C(18)H(15)P)], the Pd(II) atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenyl-phosphan-yl)benzene-thiol-ate ligand and the other two by a P atom from a triphenyl-phosphine ligand and an S atom from a pyridine-2-thiol-ate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and inter-molecular C-Hâ¯Ï and Ï-Ï inter-actions are observed. The pyridyl ring is equally disordered over two positions.
[2-(Diphenyl-phosphan-yl)benzene-thiol-ato-κP,S](pyridine-2-thiol-ato-κS)(triphenyl-phosphine-κP)palladium(II).
[2-(二苯基膦基)苯硫醇-酸根-κP,S](吡啶-2-硫醇-酸根-κS)(三苯基膦-κP)钯(II)
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作者:RÃos-Sanchez Raúl, Hernández-Ortega Simón, Morales-Morales David, Avila-Sorrosa Alcives
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Aug 28; 66(Pt 9):m1170-1 |
| doi: | 10.1107/S160053681003357X | ||
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