In the centrosymmetric binuclear title complex, [Hg(2)Cl(4)(C(12)H(10)N(6))(2)], the Hg(II) ion is five-coordinated by two N atoms and three chloride ions with a distorted square-pyramidal geometry. In the complex, there is an intra-molecular N-Hâ¯N hydrogen bond. In the crystal, the binuclear units are connected by inter-molecular N-Hâ¯Cl hydrogen bonds, as well as Ï-Ï stacking inter-actions [centroid-centroid distances = 3.526â (2) and 3.696â (2)â à ], forming a two-dimensional layered structure parallel to (010).
Di-μ-chlorido-bis-{[4-amino-3,5-bis-(2-pyrid-yl)-4H-1,2,4-triazole-κN]chloridomercury(II)}.
二-μ-氯-双-{[4-氨基-3,5-双-(2-吡啶基)-4H-1,2,4-三唑-μN]氯汞(II)}
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作者:Guo Jian, Tang Min, Chen Jing, Li Cheng-Peng
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Sep 1; 67(Pt 9):m1180 |
| doi: | 10.1107/S1600536811029886 | ||
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