Di-μ-chlorido-bis-{[4-amino-3,5-bis-(2-pyrid-yl)-4H-1,2,4-triazole-κN]chloridomercury(II)}.

二-μ-氯-双-{[4-氨基-3,5-双-(2-吡啶基)-4H-1,2,4-三唑-μN]氯汞(II)}

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作者:Guo Jian, Tang Min, Chen Jing, Li Cheng-Peng
In the centrosymmetric binuclear title complex, [Hg(2)Cl(4)(C(12)H(10)N(6))(2)], the Hg(II) ion is five-coordinated by two N atoms and three chloride ions with a distorted square-pyramidal geometry. In the complex, there is an intra-molecular N-H⋯N hydrogen bond. In the crystal, the binuclear units are connected by inter-molecular N-H⋯Cl hydrogen bonds, as well as π-π stacking inter-actions [centroid-centroid distances = 3.526†(2) and 3.696†(2)†à ], forming a two-dimensional layered structure parallel to (010).

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