The title compound, [Sr(C(10)H(6)NO(2))(2)(H(2)O)(2)](n), contains an eight-coordinate Sr(II) ion displaying a distorted square-anti-prismatic geometry, two quinoline-3-carboxyl-ate ligands and two terminal water mol-ecules. The Sr(II) atom is surrounded by six carboxyl-ate O atoms from four separate quinoline-3-carboxyl-ate ligands and two O atoms from two coordinated water mol-ecules. The bridging carboxyl-ate O atoms [Sr-O = 2.498â (3) and 2.495â (3)â à ] link Sr(II) atoms, forming a chain substructure extending along the c axis. The chains are linked by O-Hâ¯N and O-Hâ¯O hydrogen bonds, giving a three-dimensional framework structure.
catena-Poly[[diaqua-strontium]-bis-(μ-quinoline-3-carboxyl-ato)].
catena-Poly[[二水合锶]-双-(α-喹啉-3-羧酸根)]
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作者:Miao Dong-Liang, Li Shi-Jie, Song Wen-Dong, Ma Xiao-Tian, Li Xiao-Fei
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Oct 1; 67(Pt 10):m1386-7 |
| doi: | 10.1107/S1600536811036610 | ||
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