catena-Poly[[diaqua-strontium]-bis-(μ-quinoline-3-carboxyl-ato)].

catena-Poly[[二水合锶]-双-(α-喹啉-3-羧酸根)]

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作者:Miao Dong-Liang, Li Shi-Jie, Song Wen-Dong, Ma Xiao-Tian, Li Xiao-Fei
The title compound, [Sr(C(10)H(6)NO(2))(2)(H(2)O)(2)](n), contains an eight-coordinate Sr(II) ion displaying a distorted square-anti-prismatic geometry, two quinoline-3-carboxyl-ate ligands and two terminal water mol-ecules. The Sr(II) atom is surrounded by six carboxyl-ate O atoms from four separate quinoline-3-carboxyl-ate ligands and two O atoms from two coordinated water mol-ecules. The bridging carboxyl-ate O atoms [Sr-O = 2.498†(3) and 2.495†(3)†à ] link Sr(II) atoms, forming a chain substructure extending along the c axis. The chains are linked by O-H⋯N and O-H⋯O hydrogen bonds, giving a three-dimensional framework structure.

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