The title compound, (C(5)H(6)N)[Cr(C(2)O(4))(2)(H(2)O)(2)], contains one protonated pyridine mol-ecule and one [Cr(C(2)O(4))(2)(H(2)O)(2)](-) complex anion in the asymmetric unit. The Cr(III) in the complex anion is coordinated in a distorted octa-hedral environment by two O atoms from two cis water mol-ecules and four O atoms from two chelating oxalate dianions. The crystal packing is stabilized by inter-molecular N-Hâ¯O(oxalate) and O-Hâ¯O(oxalate) hydrogen bonds and by Ï-Ï stacking inter-actions (centroid-centroid distance = 3.602â à ) between pyridine rings, thereby building up a three-dimensional network.
Pyridinium cis-diaqua-bis-(oxalato-κ(2)O,O')chromate(III).
吡啶顺-diaqua-bis-(草酸根-γ(2)O,O')铬酸盐(III)
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作者:Nenwa Justin, Befolo Olivier, Gouet Bebga, Mbarki Mohammed, Fokwa Boniface P T
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Nov 1; 68(Pt 11):m1434 |
| doi: | 10.1107/S1600536812044303 | ||
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