Pyridinium cis-diaqua-bis-(oxalato-κ(2)O,O')chromate(III).

吡啶顺-diaqua-bis-(草酸根-γ(2)O,O')铬酸盐(III)

阅读:4
作者:Nenwa Justin, Befolo Olivier, Gouet Bebga, Mbarki Mohammed, Fokwa Boniface P T
The title compound, (C(5)H(6)N)[Cr(C(2)O(4))(2)(H(2)O)(2)], contains one protonated pyridine mol-ecule and one [Cr(C(2)O(4))(2)(H(2)O)(2)](-) complex anion in the asymmetric unit. The Cr(III) in the complex anion is coordinated in a distorted octa-hedral environment by two O atoms from two cis water mol-ecules and four O atoms from two chelating oxalate dianions. The crystal packing is stabilized by inter-molecular N-H⋯O(oxalate) and O-H⋯O(oxalate) hydrogen bonds and by π-π stacking inter-actions (centroid-centroid distance = 3.602†à ) between pyridine rings, thereby building up a three-dimensional network.

特别声明

1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。

2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。

3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。

4、投稿及合作请联系:info@biocloudy.com。