The structure of the title compound, [Cd(3)Cl(6)(C(15)H(15)NO(2))(2)(CH(4)O)(2)](n), is based on a layered zigzag polymeric chain along the c axis. The Cd(II) ions are linked by double chlorine bridges alternating between one CdCl(4)(CH(3)OH)(2) and two CdCl(4)(C(15)H(15)NO(2)) octa-hedral coordination units. Additional intrachain N-Hâ¯O and O-Hâ¯Cl hydrogen-bond interactions stabilize this arrangement.
catena-Poly[[{2-meth-oxy-6-[(4-methyl-phen-yl)imino-meth-yl]phenolato}-cad-mium(II)]-di-μ(2)-chlorido-[dimethanol-cadmium(II)]-di-μ(2)-chlorido-[{2-meth-oxy-6-[(4-methyl-phen-yl)imino-meth-yl]-phenolato}cadmium(II)]-di-μ(2)-chlorido].
catena-Poly[[{2-甲氧基-6-[(4-甲基苯基)亚氨基甲基]苯酚酸根}-镉(II)]-二-α(2)-氯-[二甲醇镉(II)]-二-α(2)-氯-[{2-甲氧基-6-[(4-甲基苯基)亚氨基甲基]苯酚酸根}镉(II)]-二-α(2)-氯]
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作者:Xian Hui-Duo, Li Hua-Qiong, Liu Jian-Feng, Zhao Guo-Liang
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2008 | 起止号: | 2008 Oct 18; 64(Pt 11):m1445 |
| doi: | 10.1107/S1600536808033527 | ||
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