The crystal structure of title compound, [Eu(NO(3))(3)(C(15)H(15)NO(2))(2)], contains two Schiff base 6-meth-oxy-2-[(4-methyl-phen-yl)imino-meth-yl]phenolate (L) ligands and three independent nitrate ions that chelate to the europium(III) ion via the O atoms. The coordination number of the Eu(III) ion is ten. The L ligands chelate with a strong Eu-O(deprotonated phenolate) bond and a weak Eu-O(meth-oxy) contact, the latter can be inter-preted as the apices of the bicapped square-anti-prismatic Eu(III) polyhedron. Intra-molecular N-Hâ¯O hydrogen bonds occur.
Bis{[6-meth-oxy-2-(4-methyl-phen-yl)iminiometh-yl]phenolate-κO,O'}tris-(nitrato-κO,O')europium(III).
双{[6-甲氧基-2-(4-甲基苯基)亚氨基甲基]苯酚盐-κO,O'}三(硝酸盐-κO,O')铕(III)
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作者:Guo, Hang-Ming
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Oct 23; 66(Pt 11):m1445 |
| doi: | 10.1107/S1600536810042194 | ||
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