In the title compound, [Cu(C(8)H(8)NO)(2)], a strictly square-planar geometry about the Cu(II) metal atom is observed. Substitution of an O atom with a methyl-functionalized N atom does not significantly alter the bond distances and angles in the copper(II) complex when compared with a similar bis-(troponato)copper(II) complex. Ï-Ï stacking is observed between the tropolone rings, with inter-planar distances of 3.5039â (16) and 3.2933â (15)â à , respectively. Additional stabilisation of the structure is accomplished through C-Hâ¯O hydrogen-bonding interactions.
Bis[2-(methyl-amino)-troponato]copper(II).
双[2-(甲基氨基)托品酸]铜(II)
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作者:Steyl Gideon, Muller Theunis J, Roodt Andreas
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Nov 6; 66(Pt 12):m1508 |
| doi: | 10.1107/S1600536810043503 | ||
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