catena-Poly[[triphenyl-tin(IV)]-μ-3-methyl-phenyl-seleninato-κO:O'].

catena-聚[[三苯基锡(IV)]-α-3-甲基苯基硒化物-αO:O']

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作者:Ru Jing, Zhang Rufen
In the polymeric title coordination compound, [Sn(C(6)H(5))(3)(C(7)H(7)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms from two symmetry-related bridging seleninate ligands in axial positions and three phenyl groups in the equatorial plane. In the crystal, the complex exhibits a zigzag chain structure running parallel to the c axis. An intra-chain C-H⋯O hydrogen bond is observed.

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