In the polymeric title coordination compound, [Sn(C(6)H(5))(3)(C(7)H(7)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms from two symmetry-related bridging seleninate ligands in axial positions and three phenyl groups in the equatorial plane. In the crystal, the complex exhibits a zigzag chain structure running parallel to the c axis. An intra-chain C-Hâ¯O hydrogen bond is observed.
catena-Poly[[triphenyl-tin(IV)]-μ-3-methyl-phenyl-seleninato-κO:O'].
catena-聚[[三苯基锡(IV)]-α-3-甲基苯基硒化物-αO:O']
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作者:Ru Jing, Zhang Rufen
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Dec 1; 67(Pt 12):m1809 |
| doi: | 10.1107/S1600536811049245 | ||
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