In the title complex, [Ni(C(13)H(9)N(2)O(3))(2)(H(2)O)(2)]·2H(2)O, the Ni(II) atom, located on a twofold rotation axis, is in a distorted octa-hedral geometry, defined by four N atoms from two 2-hy-droxy-5-[(pyridin-2-yl)methyl-idene-amino]-benzoate ligands and two O atoms from two water mol-ecules. In the crystal, inter-molecular O-Hâ¯O hydrogen bonds link the complex mol-ecules and uncoordinated water mol-ecules into a three-dimensional network. Intra-molecular O-Hâ¯O hydrogen bonds are present between the hy-droxy and carboxyl-ate groups.
Diaqua-bis-{2-hy-droxy-5-[(pyridin-2-yl)methyl-idene-amino]-benzoato-κN,N'}nickel(II) dihydrate.
二水合双-{2-羟基-5-[(吡啶-2-基)亚甲基氨基]苯甲酸根-κN,N'}镍(II)二水合物
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作者:Zha Meiqin, Li Xing, Bing Yue, Luo Zhengbing
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Nov 13; 66(Pt 12):m1570 |
| doi: | 10.1107/S1600536810046118 | ||
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