Bis[N,N'-bis-(2,6-diisopropyl-phen-yl)ethane-1,2-diimine]-1κN,N';2κN,N'-tri-μ-trichlorido-1:2κCl:Cl-chlorido-1κCl-tetra-hydro-furan-2κO-dichromium(II) dichloro-methane 4.5-solvate.

双[N,N'-双-(2,6-二异丙基-苯-基)乙烷-1,2-二亚胺]-1μoN,N';2μoN,N'-三-μ-三氯化物-1:2μCl:Cl-氯化物-1μCl-四氢呋喃-2μO-二铬(II)二氯甲烷4.5-溶剂化物

阅读:6
作者:Peitz Stephan, Peulecke Normen, Müller Bernd H, Spannenberg Anke, Rosenthal Uwe
In the mol-ecular structure of the title compound, [Cr(2)Cl(4)(C(26)H(36)N(2))(2)(C(4)H(8)O)]·4.5CH(2)Cl(2), the two Cr(II) centers are bridged by three Cl atoms, forming a dinuclear complex. Each Cr(II) center is coordinated by one chelating bis-(2,6-diisopropyl-phen-yl)ethane-1,2-diimine ligand via both N atoms. An additional chloride ion binds to one chromium center, whereas an additional tetra-hydro-furan mol-ecule coordinates to the second Cr(II) center. The coordination geometry at each Cr(II) center can be best described as distorted octa-hedral.

特别声明

1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。

2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。

3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。

4、投稿及合作请联系:info@biocloudy.com。