In the title compound, [Sn(C(5)H(9)O(2))(2)(C(3)S(5))], the immediate environment around the Sn centre is defined by two S and two C atoms that define an approximately tetra-hedral geometry. The close approach of the pendant carbonyl O atoms [Sn-O = 2.577â (3) and 2.573â (3)â à ] increases the coordination number to six. Supra-molecular chains are formed along the a axis in the crystal structure owing to the presence of C-Hâ¯O contacts.
Bis(2-ethoxy-carbonyl-ethyl-κC,O)(2-thioxo-1,3-dithiole-4,5-dithiol-ato-κS,S)tin(IV).
双(2-乙氧基-羰基-乙基-γC,O)(2-硫代-1,3-二硫醇-4,5-二硫醇-ato-γS,S)锡(IV)
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作者:de Lima Geraldo M, Wardell Solange M S V, Wardell James L, Tiekink Edward R T
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Nov 21; 65(Pt 12):m1635-6 |
| doi: | 10.1107/S1600536809048971 | ||
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