The asymmetric unit of the title compound, C21H13ClFNO2S, contains two independent mol-ecules with similar conformations. In the mol-ecules, the thia-zole ring is essentially planar [maximum atomic deviations = 0.014â (4) and 0.023â (5)â à ] and is oriented with respect to the fluoro-phenyl ring and chloro-phenyl rings at 9.96â (18) and 70.39â (18)° in one mol-ecule and at 7.50â (18) and 68.43â (18)° in the other; the dihedral angles between the fluoro-phenyl and chloro-phenyl rings are 64.9â (2) and 64.6â (2)°, respectively. Inter-molecular C-Hâ¯O and C-Hâ¯F hydrogen bonds stabilize the three-dimensional supra-molecular architecture. Weak C-Hâ¯Ï and Ï-Ï inter-actions [centroid-centroid distance = 3.877â (3)â à ] lead to a criss-cross mol-ecular packing along the c axis.
{2-[(1,3-Benzo-thia-zol-2-yl)meth-oxy]-5-fluoro-phen-yl}(4-chloro-phen-yl)methanone.
{2-[(1,3-苯并噻唑-2-基)甲氧基]-5-氟苯基}(4-氯苯基)甲酮
阅读:5
作者:Venugopala K N, Nayak Susanta K, Govender Thavendran, Kruger Hendrik G, Maguire Glenn E M
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 Jun 8; 69(Pt 7):o1007-8 |
| doi: | 10.1107/S1600536813014621 | ||
特别声明
1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。
2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。
3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。
4、投稿及合作请联系:info@biocloudy.com。
