In the title compound, C(19)H(11)N(3)O(2)SClBr, the chromene ring system and the thia-zole ring are each approximately planar, with maximum deviations of 0.033â (3)â à and 0.006â (3)â à , respectively. The mol-ecule adopts an E configuration about the central C=N double bond. The central thia-zole ring makes dihedral angles of 9.06â (14)° and 12.07â (11)° with the chloro-substituted phenyl ring and the chromene ring, respectively. The mol-ecular structure features a short C-Hâ¯O contact, which generates an S(6) ring motif. The crystal structure is stabilized by inter-molecular N-Hâ¯O hydrogen bonds, which link the mol-ecules into chains along the b axis. Ï-Ï stacking inter-actions [centroid-centroid distance = 3.4813â (15)â à ] are also present.
(E)-6-Bromo-3-{2-[2-(4-chloro-benzyl-idene)hydrazin-yl]thia-zol-5-yl}-2H-chromen-2-one.
(E)-6-溴-3-{2-[2-(4-氯苄基亚甲基)肼基]噻唑-5-基}-2H-色烯-2-酮
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作者:Arshad Afsheen, Osman Hasnah, Lam Chan Kit, Hemamalini Madhukar, Fun Hoong-Kun
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Apr 1; 67(Pt 4):o1007-8 |
| doi: | 10.1107/S1600536811011172 | ||
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