In the title compound, C(19)H(12)BrFO(2)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane through the naphthofuran fragment. The 4-fluoro-phenyl ring is rotated out of the naphthofuran plane, making a dihedral angle of 41.65â (7)°. In the crystal, mol-ecules are linked by weak inter-molecular C-Hâ¯O and C-Hâ¯Ï inter-actions, and a short Brâ¯F contact [3.046â (2)â à ] occurs. The O atom of the sulfinyl group is disordered over two positions, with refined site-occupancy factors of 0.912â (4) and 0.088â (4).
7-Bromo-2-(4-fluoro-phen-yl)-1-(methyl-sulfin-yl)naphtho[2,1-b]furan.
7-溴-2-(4-氟苯基)-1-(甲基亚磺酰基)萘并[2,1-b]呋喃
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作者:Choi Hong Dae, Seo Pil Ja, Son Byeng Wha, Lee Uk
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Apr 2; 66(Pt 5):o1012 |
| doi: | 10.1107/S1600536810011645 | ||
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