In the title compound, C20H18O7, the dioxolane ring adopts an envelope conformation with the dimethyl-substituted C atom as the flap, and its mean plane makes a dihedral angle of 73.25â (2)° with the pyran ring mean plane. The furan ring makes dihedral angles of 67.43â (12) and 6.20â (11)° with the mean plane of the dioxolane and pyran rings, respectively. The O atom attached to the pyran ring deviates by 0.0219â (2)â à from its mean plane. In the crystal, mol-ecules are linked via C-Hâ¯O hydrogen bonds, forming chains along [010] and enclosing R 2 (2)(9) loops. They stack along the a axis with Ï-Ï inter-actions involving the 4H-chromene units [centroid-centroid distances of 3.6389â (13) and 3.6555â (13)â à ]. The terminal CH2=CH- atoms of the allyl acetate group are disordered over two sets of sites with a refined occupancy ratio of 0.717â (6):0.283â (6).
Allyl 2-(2,2-dimethyl-3a,6a-di-hydro-furo[3,2-d][1,3]dioxol-5-yl)-4-oxo-4H-chromene-3-carboxyl-ate.
2-(2,2-二甲基-3a,6a-二氢呋喃并[3,2-d][1,3]二氧杂环戊烯-5-基)-4-氧代-4H-色烯-3-羧酸烯丙酯
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作者:Fatima Zeenat, Srinivasan Thothadri, Rao Jonnalagadda Naga Siva, Raghunathan Raghavachary, Velmurugan Devadasan
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 Jul 13; 69(Pt 8):o1257-8 |
| doi: | 10.1107/S1600536813018904 | ||
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