2-{2-[(E)-(2-Benzoyl-hydrazin-1-yl-idene)meth-yl]phen-oxy}acetic acid.

2-{2-[(E)-(2-苯甲酰肼-1-亚基)甲基]苯氧基}乙酸

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作者:Fun Hoong-Kun, Chia Tze Shyang, Alafeefy Ahmed M, Abdel-Aziz Hatem A
In the title compound, C(16)H(14)N(2)O(4), the dihedral angle between the aromatic rings is 12.45†(6)°. The central C(=O)-N-N=C bridge is roughly planar (r.m.s. deviation = 0.0346†à ) and makes dihedral angles of 13.01†(7) and 0.56†(7)° with the attached phenyl and benzene rings, respectively. The acetic acid unit (r.m.s. deviation = 0.0066†à ) is twisted from its attached benzene ring [dihedral angle = 19.48†(6)°]. In the crystal, mol-ecules are linked by O-H⋯(O,N), N-H⋯O and C-H⋯O hydrogen bonds into sheets lying parallel to the bc plane. A weak aromatic π-π stacking inter-action is also observed [centroid-centroid distance = 3.7330†(7)†à ].

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