In the title compound, C(22)H(25)NO(3), the mol-ecule has a pseudo-mirror plane. The structure is a positional isomer of 2,4-bis(4-methoxy-phenyl)-3-aza-bicyclo-[3.3.1]nonan-9-one [Cox, McCabe, Milne & Sim (1985 â¶). J. Chem. Soc. Chem. Commun. pp. 626-628]. The 3-aza-bicyclo-[3.3.1]nonan-9-one moiety adopts a double chair conformation with equatorial orientations of both 2-methoxy-phenyl substituents on either side of the secondary amino group. The benzene rings are oriented at an angle of 33.86â (4)° with respect to each other and the meth-oxy groups point towards the carbonyl group. The crystal structure is stabilized by intermolecular N-Hâ¯Ï inter-actions.
2,4-Bis(2-methoxy-phenyl)-3-aza-bicyclo-[3.3.1]nonan-9-one.
2,4-双(2-甲氧基苯基)-3-氮杂双环[3.3.1]壬烷-9-酮
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作者:Parthiban P, Ramkumar V, Kim Min Sung, Son Se Mo, Jeong Yeon Tae
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 May 23; 65(Pt 6):o1383 |
| doi: | 10.1107/S1600536809018686 | ||
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