In the title compound, C(22)H(19)NO(5)S, the carbazole skeleton is nearly planar [maximum deviation = 0.043â (1)â à ] with the pyrrole ring oriented at dihedral angles of 2.32â (6) and 1.77â (6)° with respect to the adjacent benzene rings. The dihedral angle between the benzene ring of the tosyl group and the carbazole skeleton is 82.25â (5)°. Intra-molecular O-Hâ¯O hydrogen bonding results in the formation of a planar six-membered ring, which is oriented at a dihedral angle of 3.06â (4)° with respect to the adjacent carbazole skeleton. In the crystal structure, weak inter-molecular C-Hâ¯O inter-actions link the mol-ecules into infinite chains and Ï-Ï contacts between the benzene rings and between the pyrrole and benzene rings [centroid-centroid distances = 3.374â (1) and 3.730â (1)â à , respectively] may further stabilize the structure. A weak C-Hâ¯Ï inter-action is also present.
Ethyl 4-hydr-oxy-9-tosyl-9H-carbazole-3-carboxyl-ate.
4-羟基-9-甲苯磺酰基-9H-咔唑-3-羧酸乙酯
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作者:Hökelek Tuncer, Dal Hakan, Tercan BarıÅ, Gülle Sibel, Ergün Yavuz
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Jun 6; 65(Pt 7):o1515-6 |
| doi: | 10.1107/S1600536809021035 | ||
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