In the title compound, C(16)H(10)Br(2)N(2)O·H(2)O, bifurcated intra-molecular N-Hâ¯(N,O) hydrogen bonding defines the essential planarity of the main mol-ecule: the dihedral angle between the quinoline and benzene rings is 7.53â (8)°. Inter-molecular O-Hâ¯O and weak C-Hâ¯O hydrogen bonds consolidate the crystal packing, which exhibits Ï-Ï inter-actions with a distance of 3.588â (1)â à between the centroids of the aromatic rings and short Brâ¯Br contacts of 3.5757â (6)â à .
2,4-Dibromo-6-[(quinolin-8-yl-amino)-methyl-idene]cyclo-hexa-2,4-dien-1-one monohydrate.
2,4-二溴-6-[(喹啉-8-基-氨基)-亚甲基]环己-2,4-二烯-1-酮一水合物
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作者:Kawamoto Keisuke, Shibahara Takashi
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2011 | 起止号: | 2011 Dec 1; 67(Pt 12):o3380 |
| doi: | 10.1107/S1600536811048793 | ||
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