Synthesis and crystal structure of N(1),N(2)-di-methyl-ethane-dihydrazide.

N(1),N(2)-二甲基乙烷二酰肼的合成和晶体结构

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作者:Bibik Yurii S, Khomenko Dmytro M, Doroshchuk Roman O, Raspertova Ilona V, Bargan Alexandra, Lampeka Rostyslav D
The title compound, N (1),N (2)-di-methyl-ethane-dihydrazide, C(4)H(10)N(4)O(2), was obtained by the methyl-ation of oxalyl dihydrazide protected with phthalimide. The mol-ecule is essentially non-planar with a dihedral angle between the two planar hydrazide fragments of 86.5†(2)°. This geometry contributes to the formation of a multi-contact three-dimensional supra-molecular network via C-H⋯O, N-H⋯O and N-H⋯N hydrogen bonds.

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