Crystal structure of the tetra-hydro-furan disolvate of a 94:6 solid solution of [N(2),N(6)-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine]-dibromido-manganese(II) and its monophosphine oxide analogue.

The MnBr(2) complex of N(2),N(6)-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine (1·MnBr(2)) co-crystallizes with 5.69% of the monophosphine oxide analogue (1O·MnBr(2)) and two tetra-hydro-furan (THF) mol-ecules, namely [N(2),N(6)-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine]-dibromido-manganese(II)-[bis-(di-tert-butyl-phosphan-yl)({6-[(di-tert-butyl-phosphan-yl)amino]-pyridin-2-yl}amino)-phosphine oxide]di-bromido-manganese(II)-tetra-hydro-furan (0.94/0.06/2), [MnBr(2)(C(21)H(41)N(3)P(2))](0.94)[MnBr(2)(C(21)H(41)N(3)OP(2))](0.06)·2C(4)H(8)O. The 1·MnBr(2) and 1O·MnBr(2) complexes are occupationally disordered about general positions. Both complexes feature square-pyramidal coordination of the Mn(II) atoms. They are connected by weak N-H⋯Br hydrogen bonding into chains extending along [001]. The THF mol-ecules are located between the layers formed by these chains. One THF mol-ecule is involved in hydrogen bonding to an amine H atom.