The title compound, [Fe(C(5)H(5))(C(21)H(24)NO(2))], which is produced by the oxidation of 1-(4-tert-butyl-phen-yl)-2-ethyl-3-ferrocenyl-pyrrole, crystallizes as a racemic mixture in the centrosymmetric space group P2(1)/n. The central heterocyclic pyrrole ring system subtends dihedral angles of 13.7â (2)° with respect to the attached cyclo-penta-dienyl ring and of 43.6â (7)° with the major component of the disordered phenyl group bound to the N atom. The 4-tert-butyl-phenyl group, as well as the non-substituted Cp ring are disordered with s.o.f. values of 0.589â (16) and 0.411â (16), respectively. In the crystal, mol-ecules with the same absolute configuration are linked into infinite chains along the b-axis direction by O-Hâ¯O hydrogen bonds between the hy-droxy substituent and the carbonyl O atom of the adjacent mol-ecule.
rac-1-(4-tert-Butyl-phen-yl)-5-ethyl-4-ferrocenyl-5-hy-droxy-1H-pyrrol-2(5H)-one.
rac-1-(4-叔丁基苯基)-5-乙基-4-二茂铁基-5-羟基-1H-吡咯-2(5H)-酮
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作者:Biletzki Tobias, Görls Helmar, Imhof Wolfgang
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2023 | 起止号: | 2023 Mar 7; 79(Pt 4):264-266 |
| doi: | 10.1107/S2056989023001858 | ||
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