Crystal structure and Hirshfeld surface analysis of (Z)-N-{chloro-[(4-ferrocenylphen-yl)imino]-meth-yl}-4-ferrocenylaniline N,N-di-methyl-formamide monosolvate.

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作者:Sghyar Riham, Bentama Abdeslem, Haoudi Amal, Mazzah Ahmed, Mague Joel T, Hökelek Tuncer, El Hadrami El Mestafa, Sebbar Nada Kheira
The title mol-ecule, [Fe(2)(C(5)H(5))(2)(C(23)H(17)ClN(2))]·C(3)H(7)NO, is twisted end to end and the central N/C/N unit is disordered. In the crystal, several C-H⋯π(ring) inter-actions lead to the formation of layers, which are connected by further C-H⋯π(ring) inter-actions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H⋯H (60.2%) and H⋯C/C⋯H (27.0%) inter-actions. Hydrogen bonding, C-H⋯π(ring) inter-actions and van der Waals inter-actions dominate the crystal packing.

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