The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(7)O(3))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], contains one half of the complex mol-ecule. Each Cu(II) atom is five-coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, two O atoms from two 4-meth-oxy-benzoate ligands, and one water mol-ecule, forming a distorted square-pyramidal geometry. Inter-molecular O-Hâ¯O and N-Hâ¯O hydrogen bonds link the mol-ecules into layers parallel to (01). Ï-Ï inter-actions, indicated by short inter-molecular distances of 3.801â (1)â à between the centroids of the benzene rings and 3.653â (1)â à between the centroids of the pyridine rings, further stabilize the structure.
Di-μ-nicotinamide-κO:N;κN:O-bis-[aqua-bis-(4-meth-oxy-benzoato-κO)copper(II)].
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作者:Hökelek Tuncer, Süzen Yasemin, Tercan BarıÅ, Tenlik Erdinç, NecefoÄlu Hacali
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Jun 16; 66(Pt 7):m807-8 |
| doi: | 10.1107/S1600536810022415 | ||
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