Bis{(S)-(-)-N-[(2-biphen-yl)methyl-idene]-1-(4-meth-oxy-phen-yl)ethyl-amine-κN}di-chlorido-palladium(II).

The Pd(II) complex bis-{(S)-(-)-N-[(biphenyl-2-yl)methyl-idene]1-(4-meth-oxy-phen-yl)ethanamine-κN}di-chlorido-palladium(II), [PdCl(2)(C(22)H(21)NO)(2)], crystallizes in the monoclinic Sohncke space group P2(1) with a single mol-ecule in the asymmetric unit. The coordination environment around the palladium is slightly distorted square planar. The N-Pd-Cl bond angles are 91.85†(19), 88.10†(17), 89.96†(18), and 90.0†(2)°, while the Pd-Cl and Pd-N bond lengths are 2.310†(2) and 2.315†(2)†à and 2.015†(2) and 2.022†(6)†à , respectively. The crystal structure features inter-molecular N-H⋯Cl and intramolecular C-H⋯Pd inter-actions, which lead to the formation of a supramolecular framework structure.