The racemic title compound, [Fe(C(5)H(5))(C(16)H(27)O(2))], comprises an α,Ï-diol-substituted undecyl chain with a ferrocenyl substituent at at one terminus. The alkane chain is inclined to the substituted ring of the ferrocene grouping by 84.22â (13)°. The ferrocene rings are almost eclipsed and parallel. The crystal structure features O-Hâ¯O and C-Hâ¯O hydrogen bonds and C-Hâ¯Ï contacts that stack the mol-ecules along the c-axis direction. A Hirshfeld surface analysis reveals that Hâ¯H inter-actions (83.2%) dominate the surface contacts.
Synthesis, crystal structure and Hirshfeld surface analysis of 1-ferrocenylundecane-1,11-diol.
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作者:McAdam C John, Simpson Jim
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2022 | 起止号: | 2022 Jan 7; 78(Pt 2):149-153 |
| doi: | 10.1107/S205698902101358X | ||
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