The asymmetric unit of the title compound, C(16)H(14)Cl(2)N(2)O, comprises two similar mol-ecules, A and B, in which the dihedral angles between the two aromatic rings are 70.1â (3) and 73.2â (2)°, respectively. The crystal structure features short C-Hâ¯Cl and C-Hâ¯O contacts and C-Hâ¯Ï and van der Waals inter-actions. The title compound was refined as a two-component non-merohedral twin, BASF 0.1076â (5). The Hirshfeld surface analysis and two-dimensional fingerprint plots show that Hâ¯H (38.2% for mol-ecule A; 36.0% for mol-ecule B), Clâ¯H/Hâ¯Cl (24.6% for mol-ecule A; 26.7% for mol-ecule B) and Câ¯H/Hâ¯C (20.0% for mol-ecule A; 20.2% for mol-ecule B) inter-actions are the most important contributors to the crystal packing.
Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-di-chloro-1-(4-methyl-phen-yl)ethen-yl]-2-(4-meth-oxy-phen-yl)diazene.
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作者:Shikhaliyev Namiq Q, AtioÄlu Zeliha, Akkurt Mehmet, Qacar Ayten M, Askerov Rizvan K, Bhattarai Ajaya
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2021 | 起止号: | 2021 Aug 27; 77(Pt 9):965-970 |
| doi: | 10.1107/S2056989021008756 | ||
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