The asymmetric unit in the title compound, C24H26N2O3, comprises two independent mol-ecules (A and B). In molecule A, the central 2-hydroxyphenyl ring is inclined to the mean plane of the major component of the imidazolidine ring by 84.52â (14)°, and by 68.08â (9) and 47.48â (9)° to the outer phenol rings. The later are inclined to one another by 66.76â (9)° and by 78.12â (14) and 80.20â (14)° to the imidazoline ring mean plane. In molecule B, the central 2-hydroxyphenyl ring is inclined to the mean plane of the imidazolidine ring by 73.64â (10)°, and by 75.60â (8) and 38.32â (9)° to the outer phenol rings. The later are inclined to one another by 69.47â (9)° and by 82.60â (10) and 64.26â (10)° to the imidazolidine ring mean plane. In each of the independent mol-ecules, two intra-molecular O-Hâ¯N hydrogen bond form S(6) ring motifs. In disordered mol-ecule A, the O-H groups of the 2-hy-droxy-benzyl groups are also involved in intra-molecular O-Hâ¯O hydrogen bonds, with the O atom of the hy-droxy-phenyl group acting as the acceptor. In the crystal, A molecules are linked by pairs of O-Hâ¯O hydrogen bonds forming inversion dimers. These dimers are linked to the B molecules via O-Hâ¯O hydrogen bonds forming double-layered slabs lying parallel to the bc plane.
2,2'-{[2-(2-Hy-droxy-phen-yl)-4-methyl-imidazolidine-1,3-di-yl]bis-(methyl-ene)}diphenol.
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作者:Rivera Augusto, Cárdenas Lorena, RÃos-Motta Jaime, KuÄeráková Monika, DuÅ¡ek Michal
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 Jul 20; 69(Pt 8):o1295-6 |
| doi: | 10.1107/S1600536813019417 | ||
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