The mol-ecular structure of the title complex, [Ni(C(13)H(8)F(2)N(2)O)(C(14)H(32)P(2))] or Ni(oFPU)(dippe), where oFPU is the dianion of bis-(2-fluoro-phen-yl)urea and dippe is 1,2-bis-(di-iso-propyl-phosphino)ethane, comprises an Ni(II) atom with a distorted square-planar coordination environment (geometry index Ï(4) = 0.195). One of the fluoro-phenyl rings of the oFPU ligand is disordered over two sets of sites in an 0.832â (7):0.168â (7) ratio. The crystal structure displays C-Hâ¯O and C-Hâ¯F hydrogen-bonding inter-actions, leading to chains with R (2) (2)(12) motifs extending parallel to [100]. The title compound might be of inter-est with respect to the production of urea and carbamate derivatives of nickel(II).
[1,2-Bis(diiso-propyl-phosphan-yl)ethane-κ(2) P,P'](2-fluoro-N-{[(2-fluoro-phen-yl)aza-nid-yl]carbon-yl}anilinido-κ(2) N,N')nickel(II).
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作者:Flores-Alamo Marcos, Perez-Ortiz Francisco J, Arevalo Alma, Garcia Juventino J
| 期刊: | IUCrdata | 影响因子: | 0.000 |
| 时间: | 2020 | 起止号: | 2020 May 19; 5(Pt 5):x200649 |
| doi: | 10.1107/S2414314620006495 | ||
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