The 1,4-di-hydro-pyridine ring of the title compound, C(24)H(29)F(2)NO(4), adopts a distorted boat conformation, while the cyclo-hexene ring is in an almost twist-boat conformation. In the crystal, N-Hâ¯O and C-Hâ¯O hydrogen bonds as well as C-Hâ¯Ï inter-actions connect mol-ecules, forming layers parallel to the (100) plane. These layers are linked by van der Waals forces and C-Hâ¯F inter-actions, which consolidate the crystal structure. Hirshfeld surface analysis shows the major contributions to the crystal packing are from Hâ¯H (54.1%), Fâ¯H/Hâ¯F (16.9%), Oâ¯H/Hâ¯O (15.4%) and Câ¯H/Hâ¯C (12.6%) contacts.
Synthesis, crystal structure and Hirshfeld surface analysis of tert-butyl 4-[4-(di-fluoro-meth-oxy)phen-yl]-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa-hydro-quinoline-3-carboxyl-ate.
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作者:Pehlivanlar Ezgi, Yıldırım Sema Ãztürk, ÅimÅek Rahime, Akkurt Mehmet, Butcher Ray J, Bhattarai Ajaya
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2023 | 起止号: | 2023 Jun 30; 79(Pt 7):664-668 |
| doi: | 10.1107/S2056989023005455 | ||
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