The title compound, C(3)H(6)N(4)O(2), exhibits partial disorder with the refined occupancy ratios of the two components being 0.582â (5):0.418â (5). In the major component, the nitroso groups have a relative syn spatial arrangement [O=Nâ¯N=O pseudo-torsion angle = 1.1â (4)°], whereas the other component has an anti disposition [177.6â (1)°]. The N-N=O moieties are almost coplanar with a dihedral angle of 5.3â (3)°, while in the minor occupied set of atoms, this angle is 8 (1)°. In both components, the imidazolidine ring adopts a twisted conformation on the C-C bond and the crystal structure shows the strain of this ring according to the N-CH(2)-CH(2)-N torsion angles [25.9â (5) and -23.8â (7)°]. In the crystal, molecules are linked by weak C-Hâ¯O hydrogen bonds.
1,3-Dinitro-soimidazolidine.
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作者:Rivera Augusto, Quiroga Diego, RÃos-Motta Jaime, DuÅ¡ek Michal, Fejfarová Karla
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Aug 1; 68(Pt 8):o2440 |
| doi: | 10.1107/S1600536812030796 | ||
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