1,3-Dinitro-soimidazolidine.

阅读:3
作者:Rivera Augusto, Quiroga Diego, Ríos-Motta Jaime, DuÅ¡ek Michal, Fejfarová Karla
The title compound, C(3)H(6)N(4)O(2), exhibits partial disorder with the refined occupancy ratios of the two components being 0.582†(5):0.418†(5). In the major component, the nitroso groups have a relative syn spatial arrangement [O=N⋯N=O pseudo-torsion angle = 1.1†(4)°], whereas the other component has an anti disposition [177.6†(1)°]. The N-N=O moieties are almost coplanar with a dihedral angle of 5.3†(3)°, while in the minor occupied set of atoms, this angle is 8 (1)°. In both components, the imidazolidine ring adopts a twisted conformation on the C-C bond and the crystal structure shows the strain of this ring according to the N-CH(2)-CH(2)-N torsion angles [25.9†(5) and -23.8†(7)°]. In the crystal, molecules are linked by weak C-H⋯O hydrogen bonds.

特别声明

1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。

2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。

3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。

4、投稿及合作请联系:info@biocloudy.com。