Low-temperature crystal structure of 4-chloro-1H-pyrazole.

The structure of 4-chloro-1H-pyrazole, C(3)H(3)ClN(2), at 170†K has ortho-rhom-bic (Pnma) symmetry and is isostructural to its bromo analogue. Data were collected at low temperature since 4-chloro-1H-pyrazole sublimes when subjected to the localized heat produced by X-rays. The structure displays inter-molecular N-H⋯N hydrogen bonding and the packing features a trimeric mol-ecular assembly bis-ected by a mirror plane (m normal to b) running through one chlorine atom, one carbon atom and one N-N bond. The asymmetric unit therefore consists of one and one-half 4-chloro-1H-pyrazole mol-ecules. Thus, the N-H proton is crystallographically disordered over two positions of 50% occupancy each.