In the title compound, C(15)H(15)Br(2)NO(2), two bridged tetra-hydro-furan rings adopt envelope conformations with the O atom as the flap. The pyrrolidine ring also adopts an envelope conformation with the spiro C atom as the flap. In the crystal, the mol-ecules are linked into dimers by pairs of C-Hâ¯O hydrogen bonds, thus generating R (2) (2)(18) rings. The crystal packing is dominated by Hâ¯H, Brâ¯H, Hâ¯Ï and Brâ¯Ï inter-actions. One of the Br atoms is disordered over two sites with occupation ratio of 0.833â (8):0.167â (8).
Crystal structure and Hirshfeld surface analysis of 4,5-di-bromo-6-methyl-2-phenyl-2,3,3a,4,5,6,7,7a-octa-hydro-3a,6-ep-oxy-1H-isoindol-1-one.
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作者:Mertsalov Dmitriy F, Nadirova Maryana A, Chervyakova Lala V, Grigoriev Mikhail S, Shelukho Evgeniya R, Ãelikesir Sevim Türktekin, Akkurt Mehmet, Mlowe Sixberth
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2021 | 起止号: | 2021 Feb 9; 77(Pt 3):237-241 |
| doi: | 10.1107/S205698902100116X | ||
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